Here's the first part of a megapost for Big Show which contains all of his WWE PPV matches. The entire post contains a total of 67 matches. This first part covers the years 1999 - 2002.

1999

Stone Cold vs. Vince McMahon (Steel Cage, St. Valentine’s Day Massacre 1999; Big Show’s Debut in the WWF) 2/14/1999 (223 MB)
http://rapidshare.com/files/62497180...ahon.part1.rar
http://rapidshare.com/files/62502173...ahon.part2.rar
http://rapidshare.com/files/62503139...ahon.part3.rar

Big Show vs. Mankind (Wrestlemania XV) 3/28/1999 (132 MB)
http://rapidshare.com/files/62073599..._XV_.part1.rar
http://rapidshare.com/files/62074444..._XV_.part2.rar

Big Show vs. Mankind (Boiler Room Brawl, Backlash 1999) 4/25/1999 (15 MB)
http://rapidshare.com/files/60889607...oom_Brawl_.wmv

The Union vs. The Acolytes vs. The Corporate Ministery (Over the Edge 1999) 5/23/1999 (45 MB)
http://rapidshare.com/files/61871107...edge_1999_.wmv

Big Show vs. Kane (King of the Ring 1999) 6/27/1999 (76 MB)
http://rapidshare.com/files/62473912...Ring_1999_.avi

Big Show vs. Kane (Fully Loaded, Guest ref. Hardcore Holly) 7/25/1999 (116 MB)
http://rapidshare.com/files/62494117...aded_1999_.wmv

Big Show & Undertaker vs. Kane & X-Pac (Summerslam 1999) 8/22/1999 (151 MB)
http://rapidshare.com/files/62258806...ne___X-Pac.wmv

6-Pack Challenge (Unforgiven 1999) 9/26/1999 (236 MB)
http://rapidshare.com/files/62507593...999_.part1.rar
http://rapidshare.com/files/62510564...999_.part2.rar
http://rapidshare.com/files/62511616...999_.part3.rar

Big Show vs. Kane (Rebellion 1999) 10/2/1999 (80 MB)
http://rapidshare.com/files/62487239...lion_1999_.avi

Big Show vs. Team Bossman (Survivor Series 1999) 11/14/1999 (45 MB)
http://rapidshare.com/files/62498991...am_Bossman.avi

Big Show vs. HHH vs. The Rock (Survivor Series 1999) 11/14/1999 (172 MB)
http://rapidshare.com/files/62544663...Rock.part1.rar
http://rapidshare.com/files/62546900...Rock.part2.rar

Big Show vs. Big Bossman (Armageddon 1999) 12/12/1999 (70 MB)
http://rapidshare.com/files/62504678...ig_Bossman.avi

2000

Royal Rumble Match (Royal Rumble 2000) 1/24/2000 (410 MB)
http://rapidshare.com/files/62518226...000_.part1.rar
http://rapidshare.com/files/62521322...000_.part2.rar
http://rapidshare.com/files/62524529...000_.part3.rar
http://rapidshare.com/files/62529648...000_.part4.rar
http://rapidshare.com/files/62530007...000_.part5.rar

Big Show vs. The Rock (No way out 2000) 2/27/2000 (10 MB)
http://rapidshare.com/files/62515631...y_out_2000_.rm

Big Show vs. The Rock vs. Triple H vs. Mick Foley (Wrestlemania XVI) 4/2/2000 (475 MB)
http://rapidshare.com/files/62293738...000_.part1.rar
http://rapidshare.com/files/62296908...000_.part2.rar
http://rapidshare.com/files/62300169...000_.part3.rar
http://rapidshare.com/files/62303789...000_.part4.rar
http://rapidshare.com/files/62306096...000_.part5.rar

Big Show vs. Kurt Angle (Backlash 2000) 4/30/2000 (60 MB)
http://rapidshare.com/files/62530256...lash_2000_.avi

Big Show & Rikishi vs. The Dudley Boyz (Insurrextion 2000) 5/6/2000 (95 MB)
http://rapidshare.com/files/62545013...he_Dudleyz.avi

Big Show vs. Shane McMahon (Judgment Day 2000) 5/21/2000 (95 MB)
http://rapidshare.com/files/63479855...00_ .avi.html

2001

Royal Rumble Match (Royal Rumble 2001) 1/21/2001 (486 MB)
http://rapidshare.com/files/63490782...2001.part1.rar
http://rapidshare.com/files/63494089...2001.part2.rar
http://rapidshare.com/files/63497118...2001.part3.rar
http://rapidshare.com/files/63500123...2001.part4.rar
http://rapidshare.com/files/63503489...2001.part5.rar

Big Show vs. Raven (No way out 2001) 2/25/2001 (49 MB)
http://rapidshare.com/files/63504527..._out_2001_.avi

Big Show vs. Raven vs. Kane (Wrestlemania XVII) 4/1/2001 (94 MB)
http://rapidshare.com/files/66574270...XVII_.avi.html

Big Show vs. Shane McMahon (Backlash 2001) 4/29/2001 (127 MB)
http://rapidshare.com/files/68991064...1_.par t1.rar
http://rapidshare.com/files/68991857...1_.par t2.rar

Big Show vs. Bradshaw (Insurrextion 2001) 5/5/2001 (84 MB)
http://rapidshare.com/files/66576919...tion_2001_.avi

Big Show vs. Test vs. Rhyno (Judgment Day 2001) 5/20/2001 (95 MB)
http://rapidshare.com/files/62087410...2001_.wmv.html

Big Show, Albert & Billy Gunn vs. Shawn Stasiak, Hugh Morrus & Kanyon (Invasion 2001) 7/22/2001 (90 MB)
http://rapidshare.com/files/62095278...k___Kanyon.wmv

Big Show vs. Diamond Dallas Page (Rebellion 2001) 11/3/2001 (46 MB)
http://rapidshare.com/files/61849975...lion_2001_.wmv

Team WWF vs. Team Alliance (Survivor Series 2001) 11/18/2001 (379 MB)
http://rapidshare.com/files/62085848...1_. part1.rar
http://rapidshare.com/files/62089904...1_. part2.rar
http://rapidshare.com/files/62094288...1_. part3.rar
http://rapidshare.com/files/62096871...1_. part4.rar

Big Show & Kane vs. The Dudleyz (Vengeance 2001) 12/9/2001 (99 MB)
http://rapidshare.com/files/63018379...dleyz.avi.html

2002

Royal Rumble Match (Royal Rumble 2002) 1/20/2002 (204 MB)
http://rapidshare.com/files/63893987...2002.part1.rar
http://rapidshare.com/files/63896501...2002.part2.rar
http://rapidshare.com/files/63896608...2002.part3.rar

Big Show vs. Stone Cold (Insurrextion 2002) 5/4/2002 (163 MB)
http://rapidshare.com/files/65554265...Cold.part1.rar
http://rapidshare.com/files/65556716...Cold.part2.rar

Big Show & Ric Flair vs. Stone Cold (Judgment Day 2002) 5/19/2002 (308 MB)
http://rapidshare.com/files/61862396...002_.part1.rar
http://rapidshare.com/files/61865473...002_.part2.rar
http://rapidshare.com/files/61868371...002_.part3.rar
http://rapidshare.com/files/61868657...002_.part4.rar

Big Show vs. Booker T (Vengeance 2002) 7/21/2002 (31 MB)
http://rapidshare.com/files/68985104...nce_2002_.rmvb

Big Show vs. Brock Lesnar (Survivor Series 2002) 11/17/2002 (88 MB)
http://rapidshare.com/files/62312115...es_200 2_.wmv

Big Show vs. Kurt Angle (Armageddon 2002) 12/15/2002 (33 MB)
http://rapidshare.com/files/20220450...ddon_2002_.ASF

Part II of this post will come in a few weeks.